Refractory Ceramic Fibres Profile

FIBERS AND DUSTS  POSSIBLE CARCINOGEN (IARC 2B)

CAS No. 142844-00-6
IARC Monograph Vol. 43, 1988 (Group 2B)
IARC Monograph Vol. 81, 2002 (Group 2B)

Refractory Ceramic Fibres Profile

General Information

Refractory ceramic fibres (RCFs) belong to a class of fibres called man-made vitreous fibres, which are primarily valued for their insulating qualities.[1] Raw refractory ceramic fibres are white or gray fibrous materials supplied in bulk fibre, blanket form, or contained in a solid product.[2]

RCFs are produced when raw materials (kaolin clay, Al2O3, SiO2 and sometimes ZrO2) are melted, then spun or blown into alumino-silicate fibres with average diameters between 1.2 to 3.5 micrometers (μm).[2] The fibres differ from natural mineral fibres like asbestos in that they have an amorphous structure (i.e. not crystalline) and they tend to be less durable.[2,3] At temperatures above 1,000°C, RCFs can be transformed into crystalline silica (cristobalite).[2] Please refer to the CAREX Canada profiles for Silica (Crystalline) and Asbestos for more information about these substances.

Refractory ceramic fibres have been classified by the International Agency for Research on Cancer (IARC) as Group 2B, possibly carcinogenic to humans, based on an increased risk of lung cancer and mesothelioma in experimental animals.[1] Pleural plaques, common in asbestos-exposed workers, may also arise in people working with RCFs.[1]

Additional adverse health effects from inhalation exposure to RCFs include respiratory irritation, often resulting in sore throat, nasal congestion, and cough.[2] Dermal exposure can result in contact dermatitis and itching.[4]

Regulations and Guidelines

Occupational Exposure Limits (OEL)[5,6,7,8,9,10,11,12,13,14,15,16,17,18,19]

Canadian Jurisdictions OEL (f/cc)
Canada Labour Code 0.2
AB, BC, MB
NL, NS, PE, NT
0.2
ON 0.5
QC 1
NU, SK 0.2 [ds]
NB
YT Not listed
Other Jurisdiction OEL (f/cc)
ACGIH 2018 TLV 0.2
f/cc = fibres per cubic centimeter, where fibres are longer than 5 micrometers (µm) and have aspect ration of 3:1 or greater
ds = designated substance
ACGIH = American Conference of Governmental Industrial Hygienists
TLV = threshold limit value

Canadian Environmental Guidelines

Jurisdiction Limit Year
Residential Indoor Air Quality Minimize exposure during renovations and installations.
Materials and products to be examined for deterioration.
1987[20]

Refractory ceramic fibres were not included in other Canadian government environmental guidelines reviewed.[21,22,23]

Canadian Agencies/Organizations

Agency Designation/Position Year
CEPA Schedule 1, paragraph ‘c’ (human health) 1999[24]
CEPA = Canadian Environmental Protection Act

Refractory ceramic fibres were not included in other Canadian government chemical listings reviewed.[25,26]

Main Uses

Because of their high thermal resistance, refractory ceramic fibres are used in high temperature applications such as furnace linings and doors, kilns, catalytic converters, brake pads, and heat shields.[2]

Canadian Production and Trade

There are several organizations in Canada that currently produce or use refractory ceramic fibers. These include Canadian Ferro Refractories Inc., FibreCast Inc., Pyrotek Inc., Thermal Ceramics, and Wolf Steel Ltd.[27]

Environmental Exposures Overview

The general public’s exposure to refractory ceramic fibres is expected to be low. However, uncertainty about releases and environmental concentrations prompted the Canadian Environmental Protection Act (CEPA) to conclude in 1993 that RCFs may enter the environment in quantities or under conditions that may constitute a danger in Canada to human life or health.[3] Potential sources of environmental exposure include inhaling fibres when materials containing RCFs are physically disturbed.[4]

Lack of data on RCF concentrations in Canadian air, water, sediment, or soil prompted an agreement between the Canadian government and the RCF industry to monitor environmental exposures for a five year period, originally beginning in 2002 but later updated and resigned in 2006 and 2013, respectively.[28,29] Annual reports from the agreement found that airborne RCF levels were significantly below the maximum allowable fenceline air concentration (0.05 fibres/cc), and that all companies implemented procedures to ensure proper maintenance and inspection of pollution control equipment. [27]

RCF releases are not reportable to the National Pollutant Release Inventory.[30] One consumer product containing RCF (an automotive sealant) was found in the US Household Products Database.[31]

Occupational Exposures Overview

Inhalation is the most important route of exposure to refractory ceramic fibres in occupational settings.[32]

CAREX Canada estimates that approximately 3,200 Canadians are exposed to RCFs in their workplaces. The largest industrial groups exposed are iron, steel, and ferro-alloy manufacturing, followed by other fabricated metal product manufacturing and motor vehicle parts manufacturing.

Workers typically exposed to RCF are involved in manufacturing, processing, or using products and equipment containing RCFs.[32] The largest occupational groups exposed to RCF include labourers in mineral and metal processing, followed by welders and related machine operators and then insulators. Other potentially exposed workers are involved in installing high-temperature insulation materials, demolition work, and maintenance and repair.[4]

Removing RCF insulating material from industrial furnaces and walls has resulted in some of the highest concentrations measured in occupational settings.[4]

For more information, see the occupational exposure estimate for refractory ceramic fibres.

Sources

Photo: Wikimedia Commons, Unifrax

1. International Agency for Research on Cancer (IARC). Monograph summary, Volume 81 (2002) (PDF)
2. The National Institute for Occupational Safety and Health (NIOSH). Criteria for a Recommended Standard – Occupational Exposure to Refractory Ceramic Fibres (2006) (PDF)
4. Agency for Toxic Substances and Disease Registry (ATSDR). Toxicological Profile for Synthetic Vitreous Fibers (2004) (PDF)
10. Government of Newfoundland and Labrador. Regulation 5,12 Occupational Health and Safety Regulations (2012)
11. Government of the Northwest Territories. Occupational Health and Safety Regulations, R-039-2015 (2016) (PDF)
13. The Canadian Legal Information Institute (CanLII). Government of Nunavut’s Occupational Health and Safety Regulations, Nu Reg 003-2016 (2010)
15. Government of Prince Edward Island. Occupational Health and Safety Act Regulations Chapter 0-1 (2013) (PDF)
17. Government of Saskatchewan. The Occupational Health and Safety Regulations, 1996 (2016) (PDF)
18. The Canadian Legal Information Institute (CanLII). Yukon’s Occupational Health Regulations, O.I.C. 1986/164 (2012) (PDF)
19. Occupational Safety and Health Administration (OSHA). Annotated PELs (2018)
22. Health Canada. Cosmetic Ingredient Hotlist (2014)
24. Heath Canada. CEPA List of Toxic Substances (1999)
25. Health Canada. Prioritization of the DSL (2006)
29. Environment and Climate Change Canada. Active Agreements: Refractory Ceramic Fibre Industry (2016)
30. Environment and Climate Change Canada. National Pollutant Release Inventory (NPRI) Facility Search (Substance name: ‘Refractory ceramic fibres’)
31. US Household Products Database (HPD). Household Products (Search term: ‘Refractory ceramic fibres’)
32. National Toxicology Program (NTP). 14th Report on Carcinogens for Ceramic Fibres (Respirable Size) (2016) (PDF)

Other Resources

  1. US National Library of Medicine. Hazardous Substances Data Bank (Search term: ‘Synthetic Vitreous Fibers’)
  2. International Programme on Chemical Safety (IPCS) INCHEM. Environmental Health Criteria 77: Man Made Mineral Fibres(1988)

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